Issue 4, 1982

Stepwise electrochemical catalysis of three successive replacements of the carbonyl group by trimethyl phosphite in a tri-iron cluster complex

Abstract

The electrochemically catalysed replacement of the carbonyl ligand by P(OMe)3 in the tri-iron cluster Fe3S2CO8L (L = C3H2S2) proceeds stepwise and leads to the clusters Fe3S2CO8–nL[P(OMe)3]n(n= 1, 2, or 3).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 243-245

Stepwise electrochemical catalysis of three successive replacements of the carbonyl group by trimethyl phosphite in a tri-iron cluster complex

A. Darchen, C. Mahé and H. Patin, J. Chem. Soc., Chem. Commun., 1982, 243 DOI: 10.1039/C39820000243

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