Schmit fragmentation of pentacyclo[6.2.2.02,704,10,05,9] dodecane-3,6-dione(1) provides a rare example of [6,2]type of intramolecular hydride shift in a conformationally constrained bicyclo[2.2.2]octane framework; the structure of one of the products(3) has been determined by X-ray crystallofraphy.
G. Mehta, V. Singh, P. N. Pandey, T. S. Cameron and Pat. A. Gardner, J. Chem. Soc., Chem. Commun., 1982, 217 DOI: 10.1039/C39820000217
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