Electrocatalysis of ligand substitution in carbonylmanganese derivatives proceeds by a cationic chain mechanism, and the driving force for each step in the catalytic cycle can be evaluated.
J. W. Hershberger and J. K. Kochi, J. Chem. Soc., Chem. Commun., 1982, 212 DOI: 10.1039/C39820000212
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