The enantiotopomerization of diarylboron salicylideneaminato-chelates proceeding via a transition state with planar tetraco-ordinate boron is associated with thermally accessible energy barriers which have been determined by use of dynamic n.m.r. spectroscopy.
M. S. Korobov, L. E. Nivorozhkin, L. E. Konstantinovsky and V. I. Minkin, J. Chem. Soc., Chem. Commun., 1982, 169 DOI: 10.1039/C39820000169
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