The structure of the orsellinate of armillol (2a), a new member of the protoilludane group and one of several sesquiterpenoid esters isolated from Armillaria mellea, was established by spectral and chemical means and confirmed by single-crystal X-ray analysis of its oxidation product, the hydroxy-aldehyde (5a).
D. Donnelly, S. Sanada, J. O'Reilly, J. Polonky, T. Prangé and C. Pascard, J. Chem. Soc., Chem. Commun., 1982, 135 DOI: 10.1039/C39820000135
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