Thermolysis of the stereospecifically deuteriated azo-compound (1D) led to bicyclo-octane (3) with complete retention and octadiene (4) with partial loss of stereochemistry.
C. J. Samuel, J. Chem. Soc., Chem. Commun., 1982, 131 DOI: 10.1039/C39820000131
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