Ultraviolet irradiation of (η-C5Me5)Re(CO)3 forms the stable complexes (η-C5Me5)Re2(µ-CO)(Co)4 and (η-C5Me5)2Re2(µ-CO)3; the length of the formal Re–Re triple bond in the latter is determined by X-ray diffraction to be 2·411 (1)Å.
J. K. Hoyano and W. A. G. Graham, J. Chem. Soc., Chem. Commun., 1982, 27 DOI: 10.1039/C39820000027
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