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Issue 3, 1982
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Anomeric effects in aziridin-1-yltetrahydropyrans


The stereochemistry of 2-aziridin-1-yltetrahydropyrans has been investigated by n.m.r. spectroscopic and dipole moment studies. Analysis of the 2-H signal, low-temperature n.m.r. data, and dipole moment measurements indicate that the aziridinyl ring is predominantly equatorial in the parent compound whereas the situation is reversed in trans-4-methyl-2-aziridin-1-yltetrahydropyran. Evidence was found for intense shielding above the aziridinyl ring.

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J. Chem. Soc., Perkin Trans. 2, 1982, 249-254
Article type

Anomeric effects in aziridin-1-yltetrahydropyrans

D. Barbry, D. Couturier and G. Ricart, J. Chem. Soc., Perkin Trans. 2, 1982, 249
DOI: 10.1039/P29820000249

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