5-Methyl-4-vinyl-1,2,3-thiadiazole can be thermally or catalytically polymerized; cross-linking of the polymer chains is possible by photochemical degradation of the thiadiazole rings leading to sulphur bridges.
O. Zimmer and H. Meier, J. Chem. Soc., Chem. Commun., 1982, 481 DOI: 10.1039/C39820000481
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