Radical-cations have been detected during the oxidation of RSCH![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
CH2(R = Et, Pri) with Cl2˙– or, ˙OH at low pH; e.s.r. parameters indicate that these possess a cyclic sulphonium structure ˙[graphic ommitted]R. Their formation from the hydroxy-adducts may involve anchimeric assistance from the sulphur atom.
B. C. Gilbert, R. O. C. Norman and P. S. Williams, J. Chem. Soc., Perkin Trans. 2, 1981, 1066 DOI: 10.1039/P29810001066
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