Terrein, a metabolite of Aspergillus terreus Thom, is biosynthesised from 3,4-dihydro-6,8-dihydroxy-3-methylisocoumarin by contraction of an aryl ring. The direction of the ring contraction has been investigated using [1,2-13C2]acetate as precursor.
R. A. Hill, R. H. Carter and J. Staunton, J. Chem. Soc., Perkin Trans. 1, 1981, 2570 DOI: 10.1039/P19810002570
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