Besides β-sitosterol-β-D-glucoside and dioscin, two new steroidal glycosides, neohecogenin glucoside and tribulosin, isolated from the aerial part of Tribulus terrestris Linn. were respectively shown to be neohecogenin-3-O-β-D-glucopyranoside (2) and neotigogenin-3-O-β-D-xylopyranosyl(1→2)-[β-D-xylopyranosyl(1→3)]-β-D-glucopyranosyl(1→4)-[α-L-rhamnopyranosyl(1→2)]-β-D-galactopyranoside (7).
S. B. Mahato, N. P. Sahu, A. N. Ganguly, K. Miyahara and T. Kawasaki, J. Chem. Soc., Perkin Trans. 1, 1981, 2405 DOI: 10.1039/P19810002405
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