The 13C n.m.r. data of the Digitalis and the Cerbera cardiac glycosides, and of ouabain and neriifolin, have been analysed. Both 13C and 1H n.m.r. results show that the 11,12-epoxide in cerbertin has an α-configuration.
L. Brown, H. T. A. Cheung, R. Thomas, T. R. Watson and J. L. E. Nemorin, J. Chem. Soc., Perkin Trans. 1, 1981, 1779 DOI: 10.1039/P19810001779
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