Solvolytic rearrangements of azabicyclic compounds. Part 1. Identification of products
Abstract
The products of solvolysis of 2β-halogeno-derivatives of 7-methyl-7-azabicyclo[2.2.1]heptane, 8-methyl-8-azabicyclo[3.2.1]octane,9-methyl-9-azabicyclo-[4.2.1]- and -[3.3.1]-nonane, and 7-methyl-7-azabicyclo[3.2.1]-octane, have been isolated and characterised. Solvolytic rearrangement of 2-bromotropinone to a 4-hydroxy-tropan-6-one is also described.