Using an asymptotic expansion, an equation has been derived for the calculation of matrix elements involved in the vibrational transition probabilities for a Morse oscillator. Resulting matrix elements and vibrational probabilities for the OH molecule agree well with those given by Heaps and Herzberg.
J. A. C. Gallas and B. P. Chakraborty, J. Chem. Soc., Faraday Trans. 2, 1981, 77, 67 DOI: 10.1039/F29817700067
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