SCHEDULED MAINTENANCE
The active oxygen species in the photo-oxidation of carbon monoxide over vanadium oxide supported on silica was confirmed to be lattice oxygen activated by photons. The reaction proceeded by a reduction–oxidation mechanism. The most effective irradiating wavelength was ca. 340 nm. The mechanism of photo-reduction of the catalyst was investigated by a kinetic study.
S. Yoshida, Y. Matsumura, S. Noda and T. Funabiki, J. Chem. Soc., Faraday Trans. 1, 1981, 77, 2237 DOI: 10.1039/F19817702237
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