The structure of molten PbCl2 has been re-examined by X-ray diffraction analysis. In molten PbCl2, each Pb atom is surrounded by three Cl atoms at an average distance of 2.63 Å as well as four Cl atoms of 3.14 Å. The average Pb—Pb interaction within 10 Å is similar to a distorted f.c.c. arrangement.
H. Morikawa, M. Miyake, Y. Takagi and F. Marumo, J. Chem. Soc., Faraday Trans. 1, 1981, 77, 1967 DOI: 10.1039/F19817701967
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