The reactions of Li[N3] or Na[N3] with some organophosphorus(V) compounds containing chloro-groups, including PCl5(py)(py = pyridine) and catechyl derivatives of PCl5, have been investigated by 31P n.m.r. spectroscopy. Several new azido-species have been identified in solution. In the PCl5(py) system, where isomerism is possible, configurations have been assigned by the method of pairwise interactions.
K. B. Dillon, A. W. G. Platt and T. C. Waddington, J. Chem. Soc., Dalton Trans., 1981, 2292 DOI: 10.1039/DT9810002292
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