Issue 7, 1981
From the journal:

Journal of the Chemical Society, Dalton Transactions

The structures and fluxional behaviour of the binary carbonyls; a new approach. Part 3. The fluxional behaviour of [Fe3(CO)11L], L = PR3 or P(OR)3

Robert E. Benfield,   Paul D. Gavens,   Brian F. G. Johnson,   Martin J. Mays,   Silvo Aime,   Luciano Milone  and  Domenico Osella  

Abstract

The stereodynamic behaviour of the complexes [Fe3(CO)11L][L = PR3 or P(OR)3], as determined by 13C n.m.r. spectroscopy over a wide temperature range, has been interpreted in terms of an icosahedral ⇌ cube-octahedral interchange of ligands of the type previously postulated for [M4(CO)12](M = Co, Rh, or lr) and their derivatives.

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Article information

DOI
https://doi.org/10.1039/DT9810001535
Article type
Paper

J. Chem. Soc., Dalton Trans., 1981, 1535-1539

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The structures and fluxional behaviour of the binary carbonyls; a new approach. Part 3. The fluxional behaviour of [Fe3(CO)11L], L = PR3 or P(OR)3

R. E. Benfield, P. D. Gavens, B. F. G. Johnson, M. J. Mays, S. Aime, L. Milone and D. Osella, J. Chem. Soc., Dalton Trans., 1981, 1535 DOI: 10.1039/DT9810001535

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