Reaction between [PtH(X)(PEt3)2] and PF2X (X = Cl, Br, or I) in CD2Cl2 at room temperature gives [(Et3P)2XPtPF2Pt(PEt2)X2], which have been characterised by 31P and 19F n.m.r. spectroscopy and by analysis. At low temperature the complexes [PtH2X2(PEt3)2] and trans-[PtX(PF2H)(PEt3)2] have been detected as intermediates, and n.m.r. parameters for the latter are given. A mechanism for the reaction is suggested.
E. A. V. Ebsworth, D. W. H. Rankin and J. D. Whitelock, J. Chem. Soc., Dalton Trans., 1981, 840 DOI: 10.1039/DT9810000840
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...