Electron spin resonance spectra of complexes of copper(II) chloride or copper(II) bromide with crown ethers exhibit hyper-fine coupling to two equivalent halogen atoms and have one g value very close to 2 showing that the ground state is A1g(dz2). γ-Irradiation of the complex of silver perchlorate with crown ether in toluene or benzene yields Ag0 centres in the crown ether.
J. Jezierska and J. B. Raynor, J. Chem. Soc., Dalton Trans., 1981, 56 DOI: 10.1039/DT9810000056
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