Issue 21, 1981

A new class of diosmium(IV) complexes containing both oxide and carboxylate bridges

Abstract

The reactions of the OsVI complexes OsO2X2(PR3)2(X = Cl or Br) with refluxing carboxylic acids produce a new class of osmium dimers of the type Os2(µ-O)(µ-O2CR)2X4(PR3)2 whose structural details have been confirmed by an X-ray diffraction study of Os2(µ-O2CCH3)2Cl4(PPh3)2.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 1120b-1121

A new class of diosmium(IV) complexes containing both oxide and carboxylate bridges

J. E. Armstrong, W. R. Robinson and R. A. Walton, J. Chem. Soc., Chem. Commun., 1981, 1120b DOI: 10.1039/C3981001120B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements