Issue 24, 1981
From the journal:

Journal of the Chemical Society, Chemical Communications

The synthesis and characterization of µ-hydrido-bis-(µ-sulphide)-ditungsten(III) complexes: the X-ray crystal structure of [HPPh3][Cl3W(µ-H)(µ-Me2S)2WCl3]

P. Michael Boorman,   Kelly J. Moynihan  and  K. Ann Kerr  

Abstract

The reaction of WCl4(Me2S)2 with Et3SiH yields Cl3W(µ-H)(µ-Me2S)2WCl2(Me2S) from which the anion [Cl3W(µ-H)(µ-Me2S)2WCl3]– can be prepared; a single-crystal X-ray diffraction study of [HPPh3][Cl3W(µ-H)-(µ-Me2S)2WCl3] shows that these complexes possess a confacial bioctahedral framework with a formal W–W triple bond of length 2·410(7)Å.

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Article information

DOI
https://doi.org/10.1039/C39810001286
Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 1286-1288

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The synthesis and characterization of µ-hydrido-bis-(µ-sulphide)-ditungsten(III) complexes: the X-ray crystal structure of [HPPh3][Cl3W(µ-H)(µ-Me2S)2WCl3]

P. M. Boorman, K. J. Moynihan and K. A. Kerr, J. Chem. Soc., Chem. Commun., 1981, 1286 DOI: 10.1039/C39810001286

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