Issue 24, 1981
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis and X-ray structural characterization of [Mo2O(S2CNEt2)6]BF4,a µ-oxo-bridged mixed oxidation state complex of molybdenum

John A. Broomhead,   Meta Sterns  and  Charles G. Young  

Abstract

The reaction of [MoO(S2CNEt2)3]BF4 and PPh3 in methanol under anaerobic conditions results in the formation of [Mo2O(S2CNEt2)6]BF4, an X-ray crystal structur of which shows a new type of µ-oxo-bridging between two molybdenum atoms each having a formal oxidation state of 4·5.

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Article information

DOI
https://doi.org/10.1039/C39810001262
Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 1262-1263

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Synthesis and X-ray structural characterization of [Mo2O(S2CNEt2)6]BF4,a µ-oxo-bridged mixed oxidation state complex of molybdenum

J. A. Broomhead, M. Sterns and C. G. Young, J. Chem. Soc., Chem. Commun., 1981, 1262 DOI: 10.1039/C39810001262

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