Issue 24, 1981
From the journal:

Journal of the Chemical Society, Chemical Communications

Pentakis(methoxycarbonyl)cyclopentadiene chemistry: unexpected replacement of Co2Me groups by H: formation and the X-ray crystal structure of a novel rhodicinium salt [Rh{η5-C5H2(CO2Me)3}2][C5(CO2Me)5]

Michael I. Bruce,   John R. Rodgers  and  Jennifer K. Walton  

Abstract

Tetra-acetatodirhodium reacts with HC5(CO2-Me)5 to give [Rh{η5-C5H2(CO2Me)3}2][C5(CO2Me)5] by unusual replacement of two CO2Me groups on each η5 ligand by H, as revealed by an X-ray structural determination.

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Article information

DOI
https://doi.org/10.1039/C39810001253
Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 1253-1254

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Pentakis(methoxycarbonyl)cyclopentadiene chemistry: unexpected replacement of Co2Me groups by H: formation and the X-ray crystal structure of a novel rhodicinium salt [Rh{η5-C5H2(CO2Me)3}2][C5(CO2Me)5]

M. I. Bruce, J. R. Rodgers and J. K. Walton, J. Chem. Soc., Chem. Commun., 1981, 1253 DOI: 10.1039/C39810001253

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