Electrochemical evidence is presented that two discrete paths of electron transfer are possible for reduction of TPPCrCl(L) where L is a substituted pyridine and TPP = tetraphenylporphryin, and that one of these involves the previously unobserved complex [TPPCr(L)2]+.
L. A. Bottomley and K. M. Kadish, J. Chem. Soc., Chem. Commun., 1981, 1212 DOI: 10.1039/C39810001212
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