Issue 22, 1981
From the journal:

Journal of the Chemical Society, Chemical Communications

Comparison of proton hyperfine coupling constants for the monomer and dimer radical cations of dimethyl sulphide and dimethyl selenide

Jih Tzong Wang  and  Ffrancon Williams  

Abstract

The finding that 1H coupling constants for Me2S+ and Me2Se+ exceed those for the corresponding dimer radical cation Me2S[graphic omitted]SMe2+ and Me2Se[graphic omitted]SMe2+ by a factor of three in each case is attributed to the anti-bonding character of the σ* semi-occupied molecular orbital in the dimeric species.

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Article information

DOI
https://doi.org/10.1039/C39810001184
Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 1184-1185

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Comparison of proton hyperfine coupling constants for the monomer and dimer radical cations of dimethyl sulphide and dimethyl selenide

J. T. Wang and F. Williams, J. Chem. Soc., Chem. Commun., 1981, 1184 DOI: 10.1039/C39810001184

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