Isomerization of the prochiral octahedral complex [FeMe(CO)2(PMe3)2(PMe2Ph)]+[BPh4]–(CO–CO cis, PMe3-PMe3trans) leads exclusively to a new chiral molecule by permutation of PMe2Ph with one of the PMe3 ligands.
M. Pankowski, W. Chodkiewicz, M. P. Simonnin and M. Pouet, J. Chem. Soc., Chem. Commun., 1981, 1071 DOI: 10.1039/C39810001071
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