Prostacyclin (prostaglandin I2) methyl ester has been prepared; the key step was an aldol reaction between a cyclopentanone enolate and the cyclopentenyl-acetaldehyde derivative (4).
R. F. Newton, S. M. Roberts, B. J. Wakefield and G. T. Woolley, J. Chem. Soc., Chem. Commun., 1981, 922 DOI: 10.1039/C39810000922
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