Broadening effects in the spectra of spin-½ nuclei, A, coupled to fast relaxing spin-½ nuclei, X, have been related to the T1 value of X and hence provide a new method for measuring this parameter at high field on account of enhanced relaxation by the chemical shift anisotropy mechanism.
F. Brady, R. W. Matthews, M. J. Forster and D. G. Gillies, J. Chem. Soc., Chem. Commun., 1981, 911 DOI: 10.1039/C39810000911
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