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Issue 17, 1981
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The relationship between the energies of carbanions, R, and their lithiated counterparts, RLi. An ab initio study

Abstract

While the methyl stabilisation energies of fifteen C1–C3 organolithium compounds, RLi, reflect (attentuation factor = 0·71) the methyl stabilisation energies of the corresponding anions, R, deviations are found when the degree of charge localisation or delocalisation is changed significantly by association with lithium.

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Article information


J. Chem. Soc., Chem. Commun., 1981, 882-884
Article type
Paper

The relationship between the energies of carbanions, R, and their lithiated counterparts, RLi. An ab initio study

P. von Ragué Schleyer, J. Chandrasekhar, A. J. Kos, T. Clark and G. W. Spitznagel, J. Chem. Soc., Chem. Commun., 1981, 882
DOI: 10.1039/C39810000882

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