Reaction of α-silylated ester magnesium enolates with aldehydes affords exclusively one diastereoisomer of the two possible β-hydroxy silanes which give pure E-unsaturated esters on acid work-up.
M. Larchevêque and A. Debal, J. Chem. Soc., Chem. Commun., 1981, 877 DOI: 10.1039/C39810000877
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