Co-ordinated chiral sulphinamides, prepared by the stereoselective oxidation of a sulphenamidocobalt(III) complex, are shown to be stable to inversion except in 3 M HCl; the crystal and molecular structure and absolute configuration of a sulphinamido-complex derived from (R)-cysteine are reported.
G. J. Gainsford, W. G. Jackson and A. M. Sargeson, J. Chem. Soc., Chem. Commun., 1981, 875 DOI: 10.1039/C39810000875
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