At high α-olefin to Et3SiH ratios at temperatures ⩽ 40 °C [(RhC5Me5)2Cl4] catalyses the formation of vinyl- and allyl-silanes; other rhodium complexes act similarly.
A. Millan, E. Towns and P. M. Maitlis, J. Chem. Soc., Chem. Commun., 1981, 673 DOI: 10.1039/C39810000673
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