Addition of chloromethyl-and methoxymethyl-disilanes, as well as hexamethyldisilane, to allene and buta-1,2-diene in the presence of a Pd (PPh3)4 catalyst gave, regioselectively, new functionalized organosilicon compounds, 2,3-bis(organosily)prop-1-enes and 2,3-bis-(organosilyl)but-1-enes, respectively.
H. Watanabe, M. Saito, N. Sotou and Y. Nagai, J. Chem. Soc., Chem. Commun., 1981, 617 DOI: 10.1039/C39810000617
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