Asymmetric chlorination of the nitrogen atom of aziridines can be carried out using achiral t-butyl hypochlorite in the presence of optically active trifluoromethylcarbinols; the absolute stereochemistry of the reaction may be correlated with the chirality of the alcohol used.
A. Forni, I. Moretti, A. V. Prosyanik and G. Torre, J. Chem. Soc., Chem. Commun., 1981, 588 DOI: 10.1039/C39810000588
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