1,5-Bis(acetoxymethyl)tricyclo[2·1.0·02,5] pentan-3-one (1) has been synthesized from 1,2-bis(acetoxymethyl)-3-diazoacetylcyclopropene by dirhodium tetra-acetate-catalysed intramolecular addition of the diazoketone to the cyclopropene double bond; an X-ray crystal structure determination of (1) reveals an extremely short bridging carbon-carbon bond.
H. Irngartinger, A. Goldmann, R. Schappert, P. Garner and P. Dowd, J. Chem. Soc., Chem. Commun., 1981, 455 DOI: 10.1039/C39810000455
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