A novel synthesis of estriol 16-glucuronide, a major estrogen involved in human pregnancy, has been accomplished using the controlled stereospecific alkaline hydrolysis of 2,4,16α-tribromoestrone and the selective glucuronidation of its hydrolysed product as key reactions.
M. Numazawa, M. Nagaoka, M. Tsuji and Y. Osawa, J. Chem. Soc., Chem. Commun., 1981, 383 DOI: 10.1039/C39810000383
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