The (20R)- and (20S)-epimers of halosterol, a naturally occurring C26-analogue of cholesterol, have been synthesized; the (20R)-epimer was identical with and the (20S)-epimer different from the sterol derived from the naturally occurring 22-dehydro derivative.
J. M. Joseph and W. R. Nes, J. Chem. Soc., Chem. Commun., 1981, 367 DOI: 10.1039/C39810000367
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