In CH2Cl2 solution the complex cis, trans-Mo(CO)2(PPh3)2(pyridine)(η2-SO2)(1) reacts to give a dinuclear complex (2); an X-ray crystal structuree determination shows that the moly-bdenum atoms are bridged by two SO2 ligands that are co-ordinated to one metal through the sulphur atom and one oxygen atom and to the second metal via thee remaining oxygen atom.
G. D. Jarvinen, G. J. Kubas and R. R. Ryan, J. Chem. Soc., Chem. Commun., 1981, 305 DOI: 10.1039/C39810000305
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