While N-acetyl-N-nitrosophenylalanine thermally decomposes by the known mechanism, its carboxylate anion undergoes facile rearrangements initiated by carboxylate attack in methanol or water to give 2-methoxy- or 2-hydroxy-3-phenylpropanoic acid, respectively.
Y. L. Chow and J. Polo, J. Chem. Soc., Chem. Commun., 1981, 297 DOI: 10.1039/C39810000297
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