Issue 6, 1981

2H n.m.r. determination of the stereochemistry of an allylic displacement in the biosynthesis of virescenol B

Abstract

Feeding of (5R)-[5-2H]mevalonate to Oospora virescens and 2H n.m.r. analysis of a derivative of the resulting virescenol B establish that the allylic displacement of pyrophosphate which generates ring c takes place with overall anti stereochemistry.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 280-282

2 H n.m.r. determination of the stereochemistry of an allylic displacement in the biosynthesis of virescenol B

D. E. Cane, H. Hasler, J. Materna, N. Cagnoli-Bellavita, P. Ceccherelli, G. F. Madruzza and J. Polonsky, J. Chem. Soc., Chem. Commun., 1981, 280 DOI: 10.1039/C39810000280

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements