Synthesis of the diterpenoid grayanol B from grayanotoxin II
Abstract
Treatment of grayanotoxin II (1) with thallium (III) acetate in acetic acid at room temperature, followed by alkaline hydrolysis, yields grayanol B (3b).
Treatment of grayanotoxin II (1) with thallium (III) acetate in acetic acid at room temperature, followed by alkaline hydrolysis, yields grayanol B (3b).
T. Kaiya, N. Shirai and J. Sakakibara, J. Chem. Soc., Chem. Commun., 1981, 22a DOI: 10.1039/C3981000022A
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