The oxidative electron-transfer chain mechanism, the SON2 mechanism, is shown to be initiated by benzoyloxyl radicals since 4-flouroanisole can be converted into a mixture of 4-methoxyphenyl acetate and benzoate (maximum ratio 10:1) in high yield by decomposing benzoyl peroxide in HOAc–KOAc at 78 °C.
L. Eberson and L. Jönsson, J. Chem. Soc., Chem. Commun., 1981, 133 DOI: 10.1039/C39810000133
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