Reaction of the methylsulphonium salts of mintsulphide (1) and isomintsulphide (2) with methyl-lithium gives the desulphurization products, via the biradical intermediates, and the [2,3]sigmatropic re-arrangement products.
T. Uyehara, T. Ohnuma, T. Saito, T. Kato, T. Yoshida and K. Takahashi, J. Chem. Soc., Chem. Commun., 1981, 127 DOI: 10.1039/C39810000127
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