Summary The relative intensities of the Co–H/D stretching vibrations in the precipitated products show that the reaction of H2 with [COII5]3–(L = CN–) in D2O produces equal amounts of [CoIIIL5H]3– and [CoIIIL5D]3– which, taken together with kinetic and electrochemical data, indicates that H2 reacts with a binuclear [CO2L10]6– ion by heterolytic fission.
M. B. Mooiman and J. M. Pratt, J. Chem. Soc., Chem. Commun., 1981, 33 DOI: 10.1039/C39810000033
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