Issue 1, 1981
From the journal:

Journal of the Chemical Society, Chemical Communications

Reaction of [Fe(CO)3(η4-cot)](cot = cyclo-octatetraene) with the tropylium ion: unusual rearrangement of cyclo-octatetraene and cycloheptatriene rings and the X-ray crystal structure of [Fe(CO)3(η4-styryl-cycloheptatriene)]

Karen Broadley,   Neil G. Connelly,   Rona M. Mills,   Mark W. Whiteley  and  Peter Woodward  

Abstract

The tropylium ion [C7H7]+ reacts with [Fe(CO)3(η4-cot)](cot = cyclo-octatetraene) to give [Fe(CO)3(η4C15H14)], X-ray studies of which reveal a styrylcyclo-heptatriene ligand; the C7-ring originates from the co-ordinated cot, the pheyl group from the tropylium ion.

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Article information

DOI
https://doi.org/10.1039/C39810000019
Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 19-20

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Reaction of [Fe(CO)3(η4-cot)](cot = cyclo-octatetraene) with the tropylium ion: unusual rearrangement of cyclo-octatetraene and cycloheptatriene rings and the X-ray crystal structure of [Fe(CO)3(η4-styryl-cycloheptatriene)]

K. Broadley, N. G. Connelly, R. M. Mills, M. W. Whiteley and P. Woodward, J. Chem. Soc., Chem. Commun., 1981, 19 DOI: 10.1039/C39810000019

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