The previously reported dependence of the heat capacity of activation for t-butyl chloride in water on mole fraction of added ethyl alcohol may be a consequence of a mechanism proposed by Albery and Robinson and the range of temperatures over which the kinetic data are obtained.
M. J. Blandamer, J. Burgess, P. P. Duce, R. E. Robertson and J. W. M. Scott, J. Chem. Soc., Chem. Commun., 1981, 13 DOI: 10.1039/C39810000013
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