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Issue 12, 1981
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Second-sphere co-ordination of neutral and cationic transition metal complexes by crown ethers

Abstract

The[ammine(η5-cyclopentadienyl) dicarbonyl-iron(II)] cation and the neutral complex amminepentacarbonyltungsten(0), form 1:1 adducts in solution with 18-crown-6 and dibenzo-18-crown-6 by virtue of hydrogen bonding between the ammine ligand in the transition metal complex and oxygen atoms of the crown ether; a crystalline adduct, [W(CO)5NH3 dibenzo-18-crown-6], has been isolated as a benzene solvate.

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Article information


J. Chem. Soc., Chem. Commun., 1981, 612-613
Article type
Paper

Second-sphere co-ordination of neutral and cationic transition metal complexes by crown ethers

H. M. Colquhoun and J. F. Stoddart, J. Chem. Soc., Chem. Commun., 1981, 612
DOI: 10.1039/C39810000612

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