The rate constants of the decarboxylation reaction of compounds (Ib–f) have been measured in water over a range of proton activities, at various temperatures. The results obtained strongly support the unimolecular decarboxyprotonation mechanism.
R. Noto, F. Buccheri, G. Consiglio and D. Spinelli, J. Chem. Soc., Perkin Trans. 2, 1980, 1627 DOI: 10.1039/P29800001627
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